Add olive oil, chicken, bourbon, soy sauce, honey, ketchup, garlic and ginger to Instant Pot in that order.
Place lid on Instant Pot and make sure valve is set to seal. Press the pressure cook button and set to high, then cook for 2 minutes. Instant Pot will take about 5-10 minutes to come to pressure then pressure cook for 2 minutes.
Meanwhile, cook all ingredients listed under rice heading in a rice cooker or on the stovetop, and mix together 1 tbsp cornstarch with 1 tbsp water in a small bowl.
Do a quick release of the pressure on the Instant Pot by flicking the switch at the top with a spoon. Open the lid when pressure gauge has dropped and the lid opens easily.
Stir cornstarch & water mixture into chicken mixture, then turn Instant Pot to saute mode, sauteeing chicken for 3-4 minutes until sauce thickens.
Serve chicken over rice, then garnish with green onions and enjoy!